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Research in the Knope lab addresses ongoing needs that lie at the intersection of energy, the environment, and sustainability. All projects involve the synthesis and in depth characterization of novel solid-state compounds.
Recent Publications
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Isolation of a chloride-capped cerium polyoxo nanocluster built from 52 metal ions
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Unlocking Arene Phosphorescence in Bismuth–Organic Materials
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Structural chemistry of penta- and hexanitrato thorium(iv) complexes isolated using N–H donors
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Back in bismuth: controlling triplet energy transfer, phosphorescence, and radioluminescence via supramolecular interactions
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Synthesis and Characterization of Cerium-Oxo Clusters Capped by Acetylacetonate.
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Efficient Europium Sensitization via Low-Level Doping in a 2-D Bismuth-Organic Coordination Polymer
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Th(IV) Bromide Complexes: A Homoleptic Aqua Ion and a Novel Th(H2O)4Br4 Structural Unit
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Reactivity of a Chloride Decorated, Mixed Valent CeIII/IV38–Oxo Cluster
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Synthesis, structural characterization, and luminescence properties of heteroleptic bismuth-organic compounds
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Using molten salts to probe outer-coordination sphere effects on lanthanide(iii)/(ii) electron-transfer reactions
Recent News
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October 2024
Tom McCusker gave his 7th semester presentation, discussing his work with lanthanide hexamers in aqueous solutions. Way to go, Tom!
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July 2024
Alice Lulich, Anamar Blanes-Dias, Sabrina Jackson, Maddie Shore, and Sara Auffant all presented posters at the International Conference on Coordination Chemistry. This is by far the biggest group that we've brought to a conference and everyone did a fantastic job!
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July 2024
Maddie Shore won a Poster Award for her poster presentation at the International Conference on Coordination Chemistry. Nice work, Maddie!
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May 2024
Meiling Spelic presented at the Graduate School Literature Seminar, discussing the complexities of actinide molten flux.
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May 2024
Alice Lulich presented at the Graduate Student Literature Seminar. Her topic was on scintillation compounds, their design and limitations.
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April 2024
The group went to Fort Hunt Elementary School and volunteered at their science night. Demos included luminescence, liquid nitrogen, and making bouncy balls. What fun!
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April 2024
Sabrina Jackson passed her qualifying exam and is now a PhD candidate. Congratulations!
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December 2023
Tom McCusker passed his original research proposal. Way to go, Tom!
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November 2023
Alice Lulich, Meiling Spelic, and Gunjan Gupta all joined the lab. Welcome to the Knope Group!
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October 2023
Our fourth years (Maddie Shore, Lulio Sans, Anamar Blanes, and Morgan McDonald) all gave wonderful 7th semester talks. Nice job, team!
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May 2023
What a special day! Congratulations to Alex, our most newly minted Ph.D. Alex recently started a position at Inpria as a Senior Staff Chemist.
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May 2023
Congratulations to our undergraduate researcher Anuj Dutta for successfully defending his honors thesis! Good luck in med school!